This water hardness calculator is created to compute the precise level of calcium (Ca²⁺) and magnesium (Mg²⁺) ions, in water using Water Hardness (mg/L as CaCO₃) = (2.5 × [Ca²⁺]) + (4.1 × [Mg²⁺]) formula.

Water hardness is typically expressed in various units, including:

  • Grains per gallon (gpg)
  • Parts per million (ppm)
  • Milligrams per liter (mg/L)
  • Millimoles per liter (mmol/L)

Water Hardness Calculator

Ca²⁺ (mg/L)Mg²⁺ (mg/L)Total Hardness (ppm as CaCO₃)Classification
3010116.3Moderately Hard
5015186.5Hard
7020257.2Very Hard
20570.4Soft
4012149.3Moderately Hard
25897.0Moderately Hard
6025245.4Very Hard
15352.1Soft
8030319.0Very Hard
4510175.0Hard
10235.7Soft
5518223.4Very Hard
355130.5Moderately Hard
9040382.4Extremely Hard
5117.9Soft

Water Hardness Calculation Formula

The formula for calculating water hardness is:

Total Hardness (as CaCO₃) = [2.497 × Ca²⁺ (mg/L)] + [4.118 × Mg²⁺ (mg/L)]

Where

  • Calcium (Ca²⁺) = 40 mg/L
  • Magnesium (Mg²⁺) = 12 mg/L

Calculation:

Total Hardness = (2.497 × 40) + (4.118 × 12)
                = 99.88 + 49.416
                = 149.296 mg/L as CaCO₃

Water Hardness Classifications:

  • Soft: 0-60 ppm
  • Moderately Hard: 61-120 ppm
  • Hard: 121-180 ppm
  • Very Hard: >180 ppm

How to Calculate the Hardness of Water?

  • Step 1: Calculate calcium hardness as CaCO₃: Ca²⁺ as CaCO₃ = 40 mg/L × 2.497 = 99.88 mg/L
  • Step 2: Calculate magnesium hardness as CaCO₃: Mg²⁺ as CaCO₃ = 15 mg/L × 4.116 = 61.74 mg/L
  • Step 3: Calculate total hardness: Total Hardness = 99.88 + 61.74 = 161.62 mg/L (ppm)
  • Step 4: Convert to grains per gallon (optional): Grains per gallon = 161.62 ÷ 17.1 = 9.45 gpg

The water sample has a hardness of 161.62 ppm (9.45 gpg), classifying it as “Hard” water.

Total Hardness Calculation by EDTA Method

The EDTA (Ethylenediaminetetraacetic acid) titration method is a widely used laboratory technique for measuring total water hardness. This method involves:

  • Sample Preparation
    • Take 50mL water sample
    • Add ammonia buffer solution
    • Add Eriochrome Black T indicator
  • Titration Process
    • Titrate with standardized EDTA solution
    • Note volume at end point (color change from wine red to blue)
Calculation: Total Hardness (mg/L as CaCO₃) = (V × N × 1000 × 100) / S Where: V = Volume of EDTA used (mL) N = Normality of EDTA S = Sample volume (mL)

How to Calculate Total Hardness of Water in PPM

Here’s the process:

  • Basic Conversion
    • 1 grain per gallon (gpg) = 17.1 ppm
    • 1 mg/L = 1 ppm
  • Calculation Example: If your water has 8 gpg hardness: Hardness in ppm = 8 gpg × 17.1 = 136.8 ppm

References

Related Chemistry Tools :

Similar Posts

Leave a Reply

Your email address will not be published. Required fields are marked *